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SECTION 1 - PRODUCT AND COMPANY
IDENTIFICATION

Product Name:

KILZ® Original

MSDS Manufacturer Number:

1000

Manufacturer Name:

Masterchem Industries LLC

Address:

3135 Old Highway M
Imperial, MO
63052-2834

General Phone Number:

(636) 942-2510

General Fax Number:

(636) 942-3663

Customer Service Phone Number:

(800) 325-3552

CHEMTREC:

For emergencies in the US, call CHEMTREC: 800-424-9300

Canutec:

In Canada, call CANUTEC: (613) 996-6666 (call collect)

MSDS Creation Date:

06/26/2006

MSDS Revision Date:

03/09/2008

NFPA

3
1
0
NA

HMIS

Health
Hazard

1

Fire Hazard

3

REACTIVITY

0

Personal Protection

x

* Chronic Health
Effects:

SECTION 2 - COMPOSITION/INFORMATION
ON INGREDIENTS

Chemical Name

CAS#

Ingredient Percent

Silicate, mica

12001-26-2

10 - 30 by weight

Nepheline Syenite

37244-96-5

1 - 5 by weight

Xylene

1330-20-7

0.1 - 1 by weight

VM&P Naphtha/Aliphatic Hydrocarbon

8032-32-4

10 - 30 by weight

Undisclosed/Proprietary

No data

10 - 30 by weight

Titanium dioxide

13463-67-7

5 - 10 by weight

Talc, Magnesium silicate hydrate

14807-96-6

1 - 5 by weight

Octanes, all isomers

No data

1 - 5 by weight

Non hazardous ingredients

No data

5 - 10 by weight

Distillates (petroleum), hydrotreated light; Kerosine -
unspecified

64742-47-8

10 - 30 by weight

Amorphous silica

7631-86-9

0.1 - 1 by weight

Nonanes

No data

5 - 10 by weight

Rutile

1317-80-2

5 - 10 by weight

SECTION 3 - HAZARDS
IDENTIFICATION

Emergency Overview:

Flammable. Irritant.

Potential Health Effects:

Eye:

May
cause irritation.

Skin:

May
cause irritation.

Inhalation:

Prolonged or excessive inhalation may cause respiratory tract
irritation.

Ingestion:

Harmful if swallowed. Ingestion can cause nausea, vomiting,
diarrhea and gastrointestinal irritation.

Chronic Health Effects:

Prolonged or repeated contact can result in defatting and
drying of the skin, which may result in skin irritation and
dermatitis (rash).
Repeated or prolonged inhalation may cause
toxic effects.

Signs/Symptoms:

Overexposure can cause headaches, dizziness, nausea, and
vomiting.

Target Organs:

Eyes. Skin. Respiratory system. Digestive system. Central
nervous system. Kidney.

Aggravation of Pre-Existing Conditions:

May
aggravate pre-existing respiratory disorders, allergy, eczema, or
skin conditions.

SECTION 4 - FIRST AID
MEASURES

Eye Contact:

Immediately flush eyes with plenty of water for 15 to 20
minutes. Get medical attention, if irritation or symptoms of
overexposure persists.

Skin Contact:

Immediately wash skin with soap and plenty of water.
Get
medical attention if irritation develops or persists.

Inhalation:

If
inhaled, remove to fresh air. If not breathing, give artificial
respiration or give oxygen by trained personnel. Seek immediate
medical attention.

Ingestion:

If
swallowed, do NOT induce vomiting. Call a physician or poison
control center immediately. Never give anything by mouth to an
unconscious person.

Other First Aid:

Due
to possible aspiration into the lungs, DO NOT induce vomiting if
ingested. Provide a glass of water to dilute the material in the
stomach. If vomiting occurs naturally, have the person lean forward
to reduce the risk of
aspiration.

SECTION 5 - FIRE FIGHTING
MEASURES

Flammable Properties:

Flammable liquid.

Flash Point:

75°F
(24.9°C)

Flash Point Method:

SETA

Lower Flammable/Explosive Limit:

1%

Upper Flammable/Explosive Limit:

7%

Fire Fighting Instructions:

Flammable. Cool fire-exposed containers using water
spray.

Extinguishing Media:

Use
alcohol foam, carbon dioxide, dry chemical, or water fog or spray
when fighting fires involving this material.

Protective Equipment:

As
in any fire, wear Self-Contained Breathing Apparatus (SCBA),
MSHA/NIOSH (approved or equivalent) and full protective
gear.

Unusual Fire Hazards:

Flammable liquid. Vapors can form an ignitable mixture with
air. Vapors can flow along surfaces to a distant ignition source and
flash back.

NFPA
Ratings:

NFPA Flammability:

3

NFPA Health:

1

NFPA Reactivity:

0

NFPA Other:

NA

SECTION 6 - ACCIDENTAL RELEASE
MEASURES

Personnel Precautions:

Use
proper personal protective equipment as listed in section
8.

Environmental Precautions:

Avoid runoff into storm sewers, ditches, and
waterways.

Spill Cleanup Measures:

Remove all sources of ignition. Absorb spill with inert
material (e.g., dry sand or earth), then place in a chemical waste
container. Provide ventilation. Collect spill with a non-sparking
tool. Place into a suitable container for
disposal.

SECTION 7 - HANDLING and
STORAGE

Handling:

Use
with adequate ventilation. Avoid breathing vapor and contact with
eyes, skin and clothing. Material will accumulate static charges
which may cause an electrical spark (ignition source). Use proper
grounding procedures.

Storage:

Store in a cool, dry, well ventilated area away from sources
of heat, combustible materials, and incompatible substances. Keep
container tightly closed when not in use.

Work Practices:

To
reduce potential for static discharge, bond and ground containers
when transferring material.

Special Handling Procedures:

Do
not reuse containers without proper cleaning or
reconditioning.

Hygiene Practices:

Wash
thoroughly after handling. Avoid contact with eyes and skin. Avoid
inhaling vapor or mist.

SECTION 8 - EXPOSURE CONTROLS,
PERSONAL PROTECTION - EXPOSURE GUIDELINES

Engineering Controls:

Use
appropriate engineering control such as process enclosures, local
exhaust ventilation, or other engineering controls to control
airborne levels below recommended exposure limits. Good general
ventilation should be sufficient to control airborne levels. Where
such systems are not effective wear suitable personal protective
equipment, which performs satisfactorily and meets OSHA or other
recognized standards. Consult with local procedures for selection,
training, inspection and maintenance of the personal protective
equipment.

Eye/Face Protection:

Wear
appropriate protective glasses or splash goggles as described by 29
CFR 1910.133, OSHA eye and face protection regulation, or the
European standard EN 166.

Skin Protection Description:

Chemical-resistant gloves and chemical goggles, face-shield
and synthetic apron or coveralls should be used to prevent contact
with eyes, skin or clothing.

Respiratory Protection:

A
NIOSH approved air-purifying respirator with an organic vapor
cartridge or canister may be permissible under certain circumstances
where airborne concentrations are expected to exceed exposure
limits. Protection provided by air purifying respirators is limited.
Use a positive pressure air supplied respirator if there is any
potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air purifying respirators
may not provide adequate protection.

Other Protective:

Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety
shower.

EXPOSURE GUIDELINES

Silicate, mica
:

Guideline ACGIH:

TLV-TWA: 3 mg/m3 (Respirable)

Guideline OSHA:

OSHA-TWA: 20 mg/m3

Xylene
:

Guideline ACGIH:

TLV-TWA: 100 ppm
TLV-STEL: 150 ppm

Guideline OSHA:

OSHA-TWA: 100 ppm

VM&P
Naphtha/Aliphatic Hydrocarbon :

Guideline ACGIH:

TLV-TWA: 300 ppm

Titanium dioxide
:

Guideline ACGIH:

TLV-TWA: 10 mg/m3

Guideline OSHA:

OSHA-TWA: 15 mg/m3

Talc, Magnesium
silicate hydrate :

Guideline ACGIH:

TLV-TWA: 2 mg/m3 (Respirable)

Guideline OSHA:

OSHA-TWA: 20 mg/m3

Distillates
(petroleum), hydrotreated light; Kerosine - unspecified
:

Guideline ACGIH:

TLV-TWA: 200 mg/m3 (Negligible aerosol
exposures)

SECTION 9 - PHYSICAL and CHEMICAL
PROPERTIES

Physical State Appearance:

Liquid.

Flash Point:

65°F
(18.3°C)

Boiling Point:

No
Data

Melting Point:

No
Data

Density:

10 -
12 Lbs./gal.

Vapor Density:

Greater than 1 (Air = 1).

pH:

No
Data

Molecular Formula:

Mixture

Molecular Weight:

Mixture

Flash Point:

75°F
(24.9°C)

Flash Point Method:

SETA

VOC Content:

Material VOC: 444 gm/l (Includes Water)
Coating VOC.: 444
gm/l (Excludes Water)

SECTION 10 - STABILITY and
REACTIVITY

Chemical Stability:

Stable under normal temperatures and pressures.

Hazardous Polymerization:

Not
reported.

Conditions to Avoid:

Heat, flames, ignition sources, and sparks. Incompatible
materials. Freezing or temperatures below 32 deg. F.

Incompatible Materials:

Oxidizing agents. Strong acids and
alkalis.

SECTION 11 - TOXICOLOGICAL
INFORMATION

RTECS Number:

VV8760000

Xylene
:

RTECS Number:

ZE2100000

Eye:

Eye
- Rabbit; Standard Draize Test. : 87 mg; mild.
Eye - Rabbit;
Standard Draize Test. : 5 mg/24H; severe. (RTECS)

Skin:

Skin
- Rabbit; Standard Draize Test. : 100%; Moderate.
Skin - Rabbit;
Standard Draize Test. : 500 mg/24H; Moderate. (RTECS)

Inhalation:

Inhalation. - Rat LC50: 5000 ppm/4H; Details of toxic effects
not reported other than lethal dose value. (RTECS)

Ingestion:

Ingestion - Rat LD50: 4300 mg/kg; Liver - other changes
Kidney, Ureter, Bladder - other changes
Ingestion - Mouse LD50:
2119 mg/kg; Details of toxic effects not reported other than lethal
dose value. (RTECS)

VM&P
Naphtha/Aliphatic Hydrocarbon :

RTECS Number:

OI6180000

Eye:

Eye's - Human: 880 ppm/15M; No effects reported.
(RTECS)

Titanium dioxide
:

RTECS Number:

XR2275000

Skin:

Skin
- Rabbit; Standard Draize Test. : 300 ug/3D; (Intermittent) mild.
(RTECS)

Ingestion:

Ingestion - Rat TDLo: 60 gm/kg; Gastrointestinal -
hypermotility, diarrhea Gastrointestinal - other changes.
(RTECS)

RTECS Number:

WW2710000

RTECS Number:

OA5504000

Amorphous silica
:

RTECS Number:

EU8655000

Eye:

Eye
- Rabbit; Standard Draize Test. : 25 mg/24H; mild.
(RTECS)

Inhalation:

Inhalation. - Rat LCLo: 2190 mg/m3/4H; Lungs, Thorax, or
Respiration - dyspnea (RTECS)

Ingestion:

Ingestion - Rat LDLo: 5 gm/kg; Nutritional and Gross
Metabolic - other changes (RTECS)

RTECS Number:

VM2940000

SECTION 12 - ECOLOGICAL
INFORMATION

Ecotoxicity:

No
ecotoxicity data was found for the product.

Environmental Fate:

No
environmental information found for this
product.

SECTION 13 - DISPOSAL
CONSIDERATIONS

Waste Disposal:

Consult with the US EPA Guidelines listed in 40 CFR Part
261.3 for the classifications of hazardous waste prior to disposal.
Furthermore, consult with your state and local waste requirements or
guidelines, if applicable, to ensure compliance. Arrange disposal in
accordance to the EPA and/or state and local
guidelines.

Important Disposal Information:

DANGER! Rags, steel wool and waste soaked with this product
may spontaneously catch fire if improperly discarded or stored. To
avoid a spontaneous combustion fire, immediately after use, place
rags, steel wool or waste in a sealed, water-filled, metal
container. Do not store unused product inside the home. For disposal
guidance, contact your household refuse collection service, fire
department, county or state government environmental control
agency.

SECTION 14 - TRANSPORT
INFORMATION

DOT Shipping Name:

Paint.

DOT UN Number:

UN1263

DOT Hazard Class:

3

DOT Packing Group:

II

SECTION 15 - REGULATORY
INFORMATION

Silicate, mica
:

TSCA Inventory Status:

Not
listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed
in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Nepheline Syenite
:

TSCA Inventory Status:

Not
listed

Canada DSL:

Listed

Xylene
:

TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed
in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

VM&P
Naphtha/Aliphatic Hydrocarbon :

TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed
in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Titanium dioxide
:

TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed
in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Talc, Magnesium
silicate hydrate :

TSCA Inventory Status:

Listed

State Regulations:

Listed in the New Jersey State Right to Know List.
Listed
in the Pennsylvania State Hazardous Substances List.

Canada DSL:

Listed

Distillates
(petroleum), hydrotreated light; Kerosine - unspecified
:

TSCA Inventory Status:

Listed

Canada DSL:

Listed

Amorphous silica
:

TSCA Inventory Status:

Listed

State Regulations:

Listed in the Pennsylvania State Hazardous Substances
List.

Canada DSL:

Listed

Rutile
:

TSCA Inventory Status:

Listed

State Regulations:

Listed in the Pennsylvania State Hazardous Substances
List.

Canada DSL:

Listed

SECTION 16 - ADDITIONAL
INFORMATION

HMIS Fire Hazard:

3

HMIS Health Hazard:

1

HMIS Reactivity:

0

HMIS Personal Protection:

x

MSDS Creation Date:

06/26/2006

MSDS Revision Date:

03/09/2008

MSDS Revision Notes:

Quarterly formula update

MSDS Author:

Actio Corporation

Disclaimer:

This
Health and Safety Information is correct to the best of our
knowledge and belief at the date of its publication but we cannot
accept liability for any loss, injury or damage which may result
from its use. We shall ensure, so far as is reasonably practicable,
that any revision of this Data Sheet is sent to all customers to
whom we have directly supplied this substance, but must point out
that it is the responsibility of any intermediate supplier to ensure
that such revision is passed to the ultimate user. The information
given in the Data Sheet is designed only as a guidance for safe
handling, storage and the use of the substance. It is not a
specification nor does it guarantee any specific properties. All
chemicals should be handled only by competent personnel, within a
controlled environment. Should further information be required, this
can be obtained through the sales office whose address is at the top
of this data sheet.

Trademark:

The
trademarks, service marks, graphics and logos used on this MSDS are
registered or unregistered trademarks of BEHR Process Corporation.
All Rights Reserved.

Copyright© 1996-2008 Actio Software Corporation. All Rights
Reserved.